Strong supramolecular binding of Li(+)@C60 with sulfonated meso-tetraphenylporphyrins and long-lived photoinduced charge separation.
نویسندگان
چکیده
A supramolecular binding occurred between lithium ion encapsulated [60]fullerene (Li(+)@C(60)) and sulfonated tetraphenylporphyrins ([MTPPS](4-) M = H(2) and Zn) in a benzonitrile solution. Photoexcitation of Li(+)@C(60)/[MTPPS](4-) results in formation of a long-lived charge-separated state by photoinduced electron transfer.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 36 شماره
صفحات -
تاریخ انتشار 2012